The Effect of Alkaline Base Activator Type on Biochar Character of Coconut Shell as a Heterogeneous Catalyst Support
DOI:
https://doi.org/10.24114/ijcst.v9i1.72439Keywords:
biochar, coconut shell, alkaline activator, heterogeneous catalystAbstract
Biochar derived from coconut shells shows promise as a support for heterogeneous catalysts. This study evaluated the effectiveness of alkaline activators (KOH 2 M, NaOH 2 M, and Ca(OH)₂ 2 M) in enhancing biochar properties. Biochar was produced by pyrolysis at 500 °C for 2 h, followed by chemical activation and calcination at the same temperature. The materials were characterized using FTIR, XRD, TGA, and Surface Area Analysis. Results indicate that alkaline activation modifies the biochar surface by increasing O–H, C=O, and C–O functional groups, improving polarity and adsorption capacity. The samples were predominantly amorphous and thermally stable, with minimal mass loss (0.149 mg). Among the activators tested, NaOH 2 M was the most effective, yielding a surface area of 306.233 m²/g, pore volume of 1.841 cc/g, and pore diameter of 1.202 nm. These properties suggest that NaOH-activated coconut shell biochar is a suitable carrier material for catalytic applications.References
1. Ditjenbun (2024) Luas Areal Tanaman Kelapa.
2. Ditjenbun (2023) Produksi Tanaman Kelapa.
3. Archana A, Vijay Pradhap Singh M, Chozhavendhan S, Gnanavel G, Jeevitha S, Muthu Kumara Pandian A (2020) Coconut Shell as a Promising Resource for Future Biofuel Production. Energy, Environ Sustain 31–43.
4. Ajien A, Idris J, Md Sofwan N, Husen R, Seli H (2023) Coconut shell and husk biochar: A review of production and activation technology, economic, financial aspect and application. Waste Manag Res 41, 37–51.
5. Khuenkaeo N, Tippayawong N (2020) Production and characterization of bio-oil and biochar from ablative pyrolysis of lignocellulosic biomass residues. Chem Eng Commun 207, 153–160.
6. Adorna J, Borines M, Dang VD, Doong RA (2020) Coconut shell derived activated biochar–manganese dioxide nanocomposites for high performance capacitive deionization. Desalination 492, 114602.
7. Sujiono EH, Zabrian D, Zurnansyah, Mulyati, Zharvan V, Samnur, Humairah NA (2022) Fabrication and characterization of coconut shell activated carbon using variation chemical activation for wastewater treatment application. Results Chem 4, 100291.
8. Zhou S, Tan C, Gao Y, Li Y, Guo S (2021) One-part alkali activated slag using Ca(OH)2and Na2CO3instead of NaOH as activator: More excellent compressive strength and microstructure. Mater Res Express 8, 0–8.
9. Bian Z, Jin G, Ji T (2021) Effect of combined activator of Ca(OH)2 and Na2CO3 on workability and compressive strength of alkali-activated ferronickel slag system. Cem Concr Compos 123, 104179.
10. Zhang C, Ji Y, Li C, Zhang Y, Sun S, Xu Y, Jiang L, Wu C (2023) The Application of Biochar for CO2 Capture: Influence of Biochar Preparation and CO2 Capture Reactors. Ind Eng Chem Res 62, 17168–17181.
11. Quan C, Wang H, Gao N (2020) Development of activated biochar supported Ni catalyst for enhancing toluene steam reforming. Int J Energy Res 44, 5749–5764.
12. Kabir Ahmad R, Anwar Sulaiman S, Yusup S, Sham Dol S, Inayat M, Aminu Umar H (2022) Exploring the potential of coconut shell biomass for charcoal production. Ain Shams Eng J 13, 101499.
13. Liu P, Sun S, Huang S, Wu Y, Li X, Wei X, Wu S (2024) KOH Activation Mechanism in the Preparation of Brewer’s Spent Grain-Based Activated Carbons. Catalysts. https://doi.org/10.3390/catal14110814
14. Yang H, Chen Z, Chen W, Chen Y, Wang X, Chen H (2020) Role of porous structure and active O-containing groups of activated biochar catalyst during biomass catalytic pyrolysis. Energy 210, 118646.
15. Sujiono EH, Zurnansyah, Zabrian D, Dahlan MY, Amin BD, Samnur, Agus J (2020) Graphene oxide based coconut shell waste: synthesis by modified Hummers method and characterization. Heliyon 6, e04568.
16. Cohen M (1978) Elements of X-Ray Diffraction Second Edition. Addison-Wesley Publishing Company












