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The Acalypha siamensis leaf as natural dye in eco-print
Abstract
The use of synthetic dyes in the textile industry has a negative impact on the environment. Therefore, it is necessary to explore natural dyes that are more environmentally friendly. The aim of this research is to find natural dyes from Acalypha siamensis leaves. In this research, compounds contained in A. siamensis extract were identified using FT-IR and GC-MS instruments, then simulations were carried out of the reactions that occurred between cinnamaldehyde (E), cellulose in cotton, and alum mordant using quantum chemistry software. ORCA 5.0.2 and Visual Molecular Dynamics (VMD). The cinnamaldehyde compound is the main constituent compound in A. siamensis leaf extract. Based on the simulation results: the reaction between cinnamaldehyde (E), cellulose in cotton fabric, and alum mordant is energetically favorable. The reaction simulation results are in line with experimental research, the reaction of cellulose in cotton fabric, alum mordant, and cinnamaldehyde produces a brownish green color. A. siamensis leaves have potential as a dye in eco-prints.
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Alsaud, N., & Farid, M. (2020). Insight into the influence of grinding on the extraction efficiency of selected bioactive compounds from various plant leaves. Applied Sciences, 10(18). https://doi.org/10.3390/APP10186362
Banerjee, S., & Banerjee, S. (2023). Anticancer Potential and Molecular Mechanisms of Cinnamaldehyde and Its Congeners Present in the Cinnamon Plant. Physiologia, 3(2), 173–207. https://doi.org/10.3390/physiologia3020013
Bide, M. (2014). Sustainable Dyeing with Synthetic Dyes. In: Muthu, S. (eds) Roadmap to Sustainable Textiles and Clothing. Textile Science and Clothing Technology. Springer, Singapore. https://doi.org/10.1007/978-981-287-065-0_3
Bintrim, R. (2008). Eco Colour: Botanical dyes for beautiful textiles by India Flint. Fashion Theory, 12(4), pp. 547–550). https://doi.org/10.2752/175174108x346986
Chetia, P., Priyadharshini, P., Manimegalai, S., Radha, P., Kumaran, K., & Tilak, M. (2023). Phytochemical analysis and extraction of natural dyes from mulberry leaves. The Pharma Innovation, 12(8), 1500–1504. https://doi.org/10.22271/tpi.2023.v12.i8r.22228
Deo, S., & Prasad, R. (2007). Effect of mordants on colour produced with spathidia flowers. Textile Trends, 29-30.
Fadilah, N. N., Fadhilah, S. K., & Nofriyaldi, A. (2024). Uji Aktivitas Gel Ekstrak Etanol Daun Teh Tehan (Acalypha siamensis) Terhadap Luka Sayat Pada Mencit Putih Jantan (Mus musculus). Jurnal Farmasi SYIFA, 2(2), 42-50. https://doi.org/10.63004/jfs.v2i2.451
Frizqia, J. S., Widi, S. G., Ferdinand, M., Zuhrotun, A., Megantara, S., & Raya Bandung-Sumedang, J. K. (2020). Uji Toksisitas Infusa Acalypha siamensis dengan Metode Brine Shrimp Lethality Test (BSLT). 14–22.
Grimme, S. (2006). Semiempirical GGA-type density functional constructed with a long-range dispersion correction. Journal of Computational Chemistry, 27(15), 1787–1799. https://doi.org/10.1002/jcc.20495
Grimme, S., Antony, J., Ehrlich, S., & Krieg, H. (2010). A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. Journal of Chemical Physics, 132(15). https://doi.org/10.1063/1.3382344
Gultom, J., Siagian, M., Tamba, U. J. R., Bukit, J., & Simorangkir, M. (2017). Ekstrak daun salaon (Indigofera tinctoria L) sebagai pewarna alami ulos dalam upaya pelestarian kearifan lokal budaya batak. J. Pendidik. Kim, 9(2), 293–298. https://doi.org/10.24114/jpkim.v9i2.7602
Gürses, A., Açıkyıldız, M., Güneş, K., Gürses, M. S., Gürses, A., Açıkyıldız, M., ... & Gürses, M. S. (2016). Colorants in health and environmental aspects. Dyes and Pigments, 69-83. https://doi.org/10.1007/978-3-319-33892-7_5
Husna, I. F. A., & Kumalaningsih, S. (2021). Optimization of ethanol concentration and time for flavonoid extraction of melinjo peel. Advances in Engineering Research, 212, 127-133. https://doi.org/10.2991/aer.k.211221.017
Helmalia, A. W., Putrid, P., & Dirpan, A. (2019). Potensi rempah-rempah tradisional sebagai sumber antioksidan alami untuk bahan baku pangan fungsional): (The potential of traditional spices as a source of natural antioxidants for functional food raw materials). Canrea Journal, 2, 26-31. https://doi.org/10.20956/canrea.v2i1.113
Humphrey, W., Dalke, A., & Schulten, K. (1996). VMD: visual molecular dynamics. Journal of Molecular Graphics, 14(1), 33-38. https://doi.org/10.1016/0263-7855(96)00018-5
İşmal, Ö. E. (2017). Greener natural dyeing pathway using a by-product of olive oil; prina and biomordants. Fibers and Polymers, 18, 773-785. https://doi.org/10.1007/s12221-017-6675-0
Kaviani, S., Shahab, S., Sheikhi, M., & Ahmadianarog, M. (2019). DFT study on the selective complexation of meso-2, 3-dimercaptosuccinic acid with toxic metal ions (Cd2+, Hg2+ and Pb2+) for pharmaceutical and biological applications. Journal of Molecular Structure, 1176, 901-907. https://doi.org/10.1016/j.molstruc.2018.09.027
Kumbhar, S., Hankare, P., Sabale, S., & Kumbhar, R. (2019). Eco-friendly dyeing of cotton with brown natural dye extracted from Ficus amplissima Smith leaves. Environmental Chemistry Letters, 17(2), 1161–1166. https://doi.org/10.1007/s10311-018-00854-w
Maciel, L. G., do Carmo, M. A. V., Azevedo, L., Daguer, H., Molognoni, L., de Almeida, M. M., Granato, D., & Rosso, N. D. (2018). Hibiscus sabdariffa anthocyanins-rich extract: Chemical stability, in vitro antioxidant and antiproliferative activities. Food and Chemical Toxicology, 113, 187–197. https://doi.org/10.1016/j.fct.2018.01.053
Meijica, G., Rameshprabu Ramaraj, & Unpaprom, Y. (2022). Natural dye (chlorophyll, anthocyanin, carotenoid, flavonoid) photosensitizer for dye-sensitized solar cell: A review. Maejo International Journal of Energy and Environmental Communication, 4(1), 12–22. https://doi.org/10.54279/mijeec.v4i1.247970
Naini, U., & Hasmah, H. (2021). Penciptaan tekstil teknik ecoprint dengan memanfaatkan tumbuhan lokal Gorontalo. Ekspresi Seni: Jurnal Ilmu Pengetahuan dan Karya Seni, 23(1), 266-276.
Nurtiana, W. (2019). Anthocyanin as Natural Colorant : A Review. Food ScienTech Journal, 1(1), 1. https://doi.org/10.33512/fsj.v1i1.6180
Ragheb, A. A., Tawfik, S., Abd -El Thalouth, J. I., & Mosaad, M. M. (2017). Development of Printing Natural Fabrics with Curcuma Natural Dye via Nanotechnology. International Journal of Pharmaceutical Sciences and Research, 8(2), 611. https://doi.org/10.13040/IJPSR.0975-8232.8(2).611-20
Rasmi, S., & Nelmira, W. (2024). Pengaruh Perbedaan fiksator tawas tunjung dan kapur sirih terhadap hasil ecoprint teknik hapazome pada bahan katun menggunakan daun pakis (Pterydophyta). Jurnal Ilmiah Multidisiplin Terpadu, 8(8), 2246–6111.
Rather, L. J., Shabbir, M., Ganie, S. A., Zhou, Q., Singh, K. P., & Li, Q. (2024). Natural dyes: Green and sustainable alternative for textile colouration. Sustainable Textile Chemical Processing, pp. 41–70. https://doi.org/10.1201/9781032629933-3
Reis, D. T., Ribeiro, I. H. S., & Pereira, D. H. (2020). DFT study of the application of polymers cellulose and cellulose acetate for adsorption of metal ions (Cd2+, Cu2+ and Cr3+) potentially toxic. Polymer Bulletin, 77(7), 3443–3456. https://doi.org/10.1007/s00289-019-02926-5
Sihotang, N. G., Saragih, R. Y., Tarigan, D. D., Yohana, M., Pakpahan, D. E. S., Silaban, S., & Simorangkir, M. (2023). Ulos batak natural dye paste from salaon leaf extract (Indigofera tinctoria L), ketapang leaf (Terminalia catappa), and cocoa fruit peel (Theobroma cacao L). J. Pendidik. Kim, 15(1), 29 - 34. https://doi.org/10.24114/jpkim.v15i1.38358
Sofyan, F., & Sy, S. (2015). The effect of waste treatment and mordant kind of lime, alum, and ferous salt on dyeing quality of silk and cotton fabrics using wastewater of gambir (Uncaria gambir Roxb). Jurnal Litbang Industri, 5(2), 79-89.
Weigend, F., & Ahlrichs, R. (2005). Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy. Physical Chemistry Chemical Physics, 7(18), 3297–3305. https://doi.org/10.1039/b508541a
Yusuf, M., Shabbir, M., & Mohammad, F. (2017). Natural colorants: Historical, processing and sustainable prospects. Natural Products and Bioprospecting, 7, 123-145. https://doi.org/10.1007/s13659-017-0119-9
Zhao, Y., & Truhlar, D. G. (2008). The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: Two new functionals and systematic testing of four M06-class functionals and 12 other functionals. Theoretical Chemistry Accounts, 120(1–3), 215–241. https://doi.org/10.1007/s00214-007-0310-x
DOI: https://doi.org/10.24114/jpkim.v16i3.66529
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